XL ANTI-SPATTER SPRAY AEROSOL Chemwatch Material Safety Data Sheet Issue Date: 24-Jun-2009 CHEMWATCH 4740-09 XC9477EC Version No:2.0 CD 2009/1 Page 1 of 7 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME XL ANTI-SPATTER SPRAY AEROSOL STATEMENT OF HAZARDOUS NATURE Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. OTHER NAMES "Product Code: CQX0341" PROPER SHIPPING NAME AEROSOLS PRODUCT USE » Application is by spray atomisation from a hand held aerosol pack. Welding anti-spatter spray. SUPPLIER Company: Northern Distributors Ltd Address: 7- 9 Allen Road Ashburton, NZL Telephone: +64 3 307 9793 Emergency Tel: 0800 2436 2255 Fax: +64 3 307 2980 Section 2 - HAZARDS IDENTIFICATION CHEMWATCH HAZARD RATINGS GHS Classification
Acute Toxicity (Oral) Category 4Carcinogen Category 2Eye Irritation Category 2BReproductive Toxicity Category 1BSkin Corrosion/Irritation Category 2
EMERGENCY OVERVIEW HAZARD DANGER Determined by Chemwatch using GHS/HSNO criteria:
Harmful if swallowedCauses skin irritationCauses eye irritationSuspected of causing cancerMay damage fertilityHarmful to terrestrial vertebrates
PRECAUTIONARY STATEMENTS Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. continued. XL ANTI-SPATTER SPRAY AEROSOL Chemwatch Material Safety Data Sheet Issue Date: 24-Jun-2009 CHEMWATCH 4740-09 XC9477EC Version No:2.0 CD 2009/1 Page 2 of 7 Section 2 - HAZARDS IDENTIFICATION
Use personal protective equipment as required. Response IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. Rinse mouth. If eye irritation persists: Get medical advice/attention. Storage Store locked up. Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS Section 4 - FIRST AID MEASURES
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)NZ EMERGENCY SERVICES: 111
SWALLOWED » Not considered a normal route of entry. - Avoid giving milk or oils. - Avoid giving alcohol. EYE » If aerosols come in contact with the eyes: - Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water. - Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. - Transport to hospital or doctor without delay. - Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. SKIN » If solids or aerosol mists are deposited upon the skin: - Flush skin and hair with running water (and soap if available). - Remove any adhering solids with industrial skin cleansing cream. - DO NOT use solvents. - Seek medical attention in the event of irritation. INHALED » If aerosols, fumes or combustion products are inhaled: - Remove to fresh air. - Lay patient down. Keep warm and rested. - Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. - If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. NOTES TO PHYSICIAN » for poisons (where specific treatment regime is absent): -------------------------------------------------------------- BASIC TREATMENT -------------------------------------------------------------- - Establish a patent airway with suction where necessary. - Watch for signs of respiratory insufficiency and assist ventilation as necessary. - Administer oxygen by non-rebreather mask at 10 to 15 L/min. - Monitor and treat, where necessary, for pulmonary oedema . for intoxication due to Freons/ Halons;
- Maintain an open airway and assist ventilation if necessary- Treat coma and arrhythmias if they occur. Avoid (adrenaline) epinephrine or other sympathomimetic amines that may precipitate ventriculararrhythmias. Tachyarrhythmias caused by increased myocardial sensitisation may be treated with propranolol, 1-2 mg IV or esmolol 25-100microgm/kg/min IV. - Monitor the ECG for 4-6 hoursB: Specific drugs and antidotes:- There is no specific antidote. Treat symptomatically. continued. XL ANTI-SPATTER SPRAY AEROSOL Chemwatch Material Safety Data Sheet Issue Date: 24-Jun-2009 CHEMWATCH 4740-09 XC9477EC Version No:2.0 CD 2009/1 Page 3 of 7 Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA » SMALL FIRE: - Water spray, dry chemical or CO2 LARGE FIRE: - Water spray or fog. FIRE FIGHTING » - Alert Fire Brigade and tell them location and nature of hazard. - May be violently or explosively reactive. - Wear breathing apparatus plus protective gloves. - Prevent, by any means available, spillage from entering drains or water course. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by FIRE/EXPLOSION HAZARD » - Non combustible. - Not considered to be a significant fire risk. - Heating may cause expansion or decomposition leading to violent rupture of containers. - Aerosol cans may explode on exposure to naked flames. Decomposition may produce toxic fumes of: carbon monoxide (CO). Combustion products include: carbon dioxide (CO2), acrolein, hydrogen chloride, phosgene, other pyrolysis products typical of burning organic material. - Non flammable liquid. - However vapour will burn when in contact with high temperature flame. - Ignition ceases on removal of flame. - May form a flammable / explosive mixture in an oxygen enriched atmosphere. FIRE INCOMPATIBILITY » - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. Personal Protective Equipment Gas tight chemical resistant suit. Section 6 - ACCIDENTAL RELEASE MEASURES EMERGENCY PROCEDURES MINOR SPILLS » - Clean up all spills immediately. - Avoid breathing vapours and contact with skin and eyes. - Wear protective clothing, impervious gloves and safety glasses. - Shut off all possible sources of ignition and increase ventilation. MAJOR SPILLS » - Remove leaking cylinders to a safe place. - Fit vent pipes. Release pressure under safe, controlled conditions - Burn issuing gas at vent pipes. - DO NOT exert excessive pressure on valve; DO NOT attempt to operate damaged valve. - Clear area of personnel and move upwind. - Alert Fire Brigade and tell them location and nature of hazard. - May be violently or explosively reactive. - Wear breathing apparatus plus protective gloves. Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING » - Avoid all personal contact, including inhalation. - Wear protective clothing when risk of exposure occurs. - Use in a well-ventilated area. - Prevent concentration in hollows and sumps. SUITABLE CONTAINER » - DO NOT use aluminium or galvanised containers. - Aerosol dispenser. - Check that containers are clearly labelled. STORAGE INCOMPATIBILITY » Methylene chloride - is a combustible liquid under certain circumstances even though there is no measurable flash point and it is difficult to ignite continued. XL ANTI-SPATTER SPRAY AEROSOL Chemwatch Material Safety Data Sheet Issue Date: 24-Jun-2009 CHEMWATCH 4740-09 XC9477EC Version No:2.0 CD 2009/1 Page 4 of 7 Section 7 - HANDLING AND STORAGE
- its is flammable in ambient air in the range 12-23%; increased oxygen content can greatly enhance fire and explosion potential- contact with hot surfaces and elevated temperatures can form fumes of hydrogen chloride and phosgene- reacts violently with active metals, aluminium, lithium, methanol,, peroxydisulfuryl difluoride, potassium, potassium tert-butoxide, sodium- forms explosive mixtures with nitric acid- is incompatible with strong oxidisers, strong caustics, alkaline earths and alkali metals- attacks some plastics, coatings and rubber- may generate electrostatic charge due to low conductivity. - Segregate from alcohol, water. - Avoid reaction with oxidising agents. STORAGE REQUIREMENTS » - Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS Source PERSONAL PROTECTION RESPIRATOR Type AXNO-P Filter of sufficient capacity EYE » No special equipment for minor exposure i.e. when handling small quantities.
OTHERWISE: For potentially moderate or heavy exposures:
- NOTE: Contact lenses pose a special hazard; soft lenses may absorb irritants and ALL lenses concentrate them. HANDS/FEET » - No special equipment needed when handling small quantities. - OTHERWISE: OTHER » No special equipment needed when handling small quantities. OTHERWISE: - Overalls. - Skin cleansing cream. - Eyewash unit. - Do not spray on hot surfaces. ENGINEERING CONTROLS » General exhaust is adequate under normal conditions. If risk of overexposure exists, wear SAA approved respirator.
Provide adequate ventilation in warehouse or closed storage areas. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Clear to hazy colourless to pale yellow liquid with an ether-like odour; not miscible with water. PHYSICAL PROPERTIES Liquid. Gas. Does not mix with water. Sinks in water.
Relative Vapour Density (air=1): Not Available
continued. XL ANTI-SPATTER SPRAY AEROSOL Chemwatch Material Safety Data Sheet Issue Date: 24-Jun-2009 CHEMWATCH 4740-09 XC9477EC Version No:2.0 CD 2009/1 Page 5 of 7 Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY » - Elevated temperatures. - Presence of open flame. - Product is considered stable. - Hazardous polymerisation will not occur. For incompatible materials - refer to Section 7 - Handling and Storage. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS GHS Hazard Phrases .
Harmful if swallowedCauses skin irritationCauses eye irritationSuspected of causing cancerMay damage fertilityHarmful to terrestrial vertebrates
TOXICITY AND IRRITATION » unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
» The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis (nonallergic). This formof dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.<</>.
METHYLENE CHLORIDE:» unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
» The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis (nonallergic). This formof dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.<</>. WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans. Inhalation (human) TCLo: 500 ppm/ 1 y - I Eye(rabbit): 10 mg - mild
CARBON DIOXIDE:» unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
Inhalation (rat) LCLo: 657190 ppm/15 mInhalation (human) TCLo: 2000 ppmInhalation (human) LCLo: 9 pph/5 m (9%)
CARCINOGEN methylene chloride
International Agency for Research on Cancer
REPROTOXIN methylene chloride
ILO Chemicals in the electronics industry
ILO Chemicals in the electronics industry
continued. XL ANTI-SPATTER SPRAY AEROSOL Chemwatch Material Safety Data Sheet Issue Date: 24-Jun-2009 CHEMWATCH 4740-09 XC9477EC Version No:2.0 CD 2009/1 Page 6 of 7 Section 12 - ECOLOGICAL INFORMATION
This material and its container must be disposed of as hazardous waste. Section 13 - DISPOSAL CONSIDERATIONS
» - DO NOT allow wash water from cleaning or process equipment to enter drains. - It may be necessary to collect all wash water for treatment before disposal. - In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. - Where in doubt contact the responsible authority. - Consult State Land Waste Management Authority for disposal. - Discharge contents of damaged aerosol cans at an approved site. - Allow small quantities to evaporate. - DO NOT incinerate or puncture aerosol cans. Section 14 - TRANSPORTATION INFORMATION
Labels Required: NON-FLAMMABLE COMPRESSED GASHAZCHEM: (1) Not applicable to the carriage of dangerous goods under RID or ADR
Air Transport IATA: ICAO/IATA Class: Maritime Transport IMDG: IMDG Class: Section 15 - REGULATORY INFORMATION REGULATIONS Regulations for ingredients XL Anti-spatter Spray Aerosol (CAS: None): No regulations applicable
methylene chloride (CAS: 75-09-2) is found on the following regulatory lists; IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk IMO Provisional Categorization of Liquid Substances - List 1: Pure or technically pure products International Agency for Research on Cancer (IARC) Carcinogens International Council of Chemical Associations (ICCA) - High Production Volume List New Zealand Hazardous Substances and New Organisms (HSNO) Act - Chemicals (single components) New Zealand Hazardous Substances and New Organisms (HSNO) Act - Hazardous Substances Register New Zealand Hazardous Substances and New Organisms (HSNO) Act - Pesticides New Zealand Hazardous Substances and New Organisms (HSNO) Act - Scheduled Toxic Substances New Zealand Inventory of Chemicals (NZIoC) New Zealand Poisons Schedule [NLV] New Zealand Workplace Exposure Standards (WES) OECD Representative List of High Production Volume (HPV) Chemicals WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
carbon dioxide (CAS: 124-38-9) is found on the following regulatory lists; CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP New Zealand Hazardous Substances and New Organisms (HSNO) Act - Dangerous Goods New Zealand Hazardous Substances and New Organisms (HSNO) Act - Hazardous Substances Register New Zealand Inventory of Chemicals (NZIoC) New Zealand Workplace Exposure Standards (WES) OECD Representative List of High Production Volume (HPV) Chemicals
Specific advice on controls required for materials used in New Zealand can be found athttp://www.ermanz.govt.nz/search/registers.html
continued. XL ANTI-SPATTER SPRAY AEROSOL Chemwatch Material Safety Data Sheet Issue Date: 24-Jun-2009 CHEMWATCH 4740-09 XC9477EC Version No:2.0 CD 2009/1 Page 7 of 7 Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE0800 POISON (0800 764 766)NZ EMERGENCY SERVICES: 111» Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
» The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 24-Jun-2009Print Date: 24-Jun-2009
REPRODUCTIVE SYSTEM -humans reproduce sexually by the union of two gametes (one each from the female and male) Gametes – sex cells – sperm and egg Egg – round, has DNA in the nucleus and a large amount of food (yolk) because it will need to survive a few days before implantation and it will need energy as it divides. -about 100 000 times larger than the sperm cell
XL ANTI-SPATTER SPRAY AEROSOL